Dependence on material choice of degradation of organic solar cells following exposure to humid air
نویسندگان
چکیده
Electron microscopy has been used to study the degradation of organic solar cells when exposed to humid air. Devices with various different combinations of commonly used organic solar cell hole transport layers and cathode materials have been investigated. In this way the ingress of water and the effect it has on devices could be studied. It was found that calcium and aluminum in the cathode both react with water, causing voids and delamination within the device. The use of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) was found to increase the degradation by easing water ingress into the device. Replacing these materials removed these degradation features. © 2015 The Authors. Journal of Polymer Science Part B: Polymer Physics published by Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016, 54, 216-224.
منابع مشابه
بهبود چگالی جریان و افزایش کارایی سلول خورشیدی پلیمری P3HT:PCBM با استفاده از نانومیله اکسید روی
Hybrid solar cells combine organic and inorganic materials with the aim of utilizing the low cost cell production of organic photovoltaics (OPV) as well as obtaining other advantages, such as tuneable absorption spectra, from the inorganic component. Whilst hybrid solar cells have the potential to achieve high power conversion efficiencies (PCE), currently obtained efficiencies are quite low. T...
متن کاملSynthesis and Application of Two Organic Dyes Based on Indoline in Dye-Sensitized Solar Cells
In this paper we sensitized two new organic days dye 1 and dye 2 based on thioindigo with phenothiazine as the electron donor group. We used acrylic acid and cyanoacrylic acid as the electron acceptor anchoring group in dye 1 and dye 2 respectively. The proposed dyes were sensitized from phenothiazine as the starting material by standard reactions and characterized by different techniques such ...
متن کاملEfficient and stable perovskite solar cells prepared in ambient air irrespective of the humidity
Poor stability of organic-inorganic halide perovskite materials in humid condition has hindered the success of perovskite solar cells in real applications since controlled atmosphere is required for device fabrication and operation, and there is a lack of effective solutions to this problem until now. Here we report the use of lead (II) thiocyanate (Pb(SCN)2) precursor in preparing perovskite s...
متن کاملFabrication of Organic Solar Cells with Branched Cauliflower-Like Nano Structures as a Back Electrode Replicated from a Natural Template of Cicada Wing Patterns
Nanostructures of noble metal materials have been used in organic solar cells for enhancement of performance and light trapping. In this study, we have introduced branched silver cauliflower-like nanopatterns as sub-wavelength structured metal grating in organic solar cells. Self-assembled fabrication process of branched nanopatterns was carried out on a bio-template of cicada wing nanonipple a...
متن کاملSynthesis and Investigation of Photovoltaic Properties of New Organic Dye in Solar Cells Device
In this paper, we designed and synthesized free-metal dyes based on indoline. The proposed dyes were synthesized from phenothiazine as the starting material by standard reactions. The chemical structure of the synthesized dye was confirmed using FT-IR, 1HNMR and DSC techniques. Spectrophotometric measurements of the organic dyes in acetonitrile and on a TiO2 substrate ...
متن کامل